Qilin Zhou
Master
mentor of Doctors
Professor
Research interests:(1) The development of new synthetic methods. (2) Organometallic chemistry directed towards organic synthesis. (3) Asymmetric catalysis. (4) Synthesis of biologically active natural and unnatural products.
E-mail:qlzhou@nankai.edu.cn
Achievement:
1.Chiral bronsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and alpha-aryl enamides: Construction of quaternary carbon atoms, Angew. Chem. Int. Ed. 2007, 46, 5565-5567.
2.Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines, J. Am. Chem. Soc. 2007, 129, 5834-5835.
3.Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols, J. Am. Chem. Soc. 2007, 129, 2248-2249.
4.Highly enantioselective hydrosilylation/cyclization of 1,6-enynes catalyzed by rhodium(I) complexes of spiro diphosphines, Angew. Chem. Int. Ed. 2007, 46, 1275-1277.
5.Ru-catalyzed asymmetric hydrogenation of racemic aldehydes via dynamic kinetic resolution: Efficient synthesis of optically active primary alcohols, J. Am. Chem. Soc. 2007, 129, 1868-1869.
6.Well-defined chiral spiro iridium/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure, J. Am. Chem. Soc. 2006, 128, 12886-12891.
7.Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of enamines using monodente spiro phosphonite ligands, J. Am. Chem. Soc. 2006, 128, 11774-11775.
8.Asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acids catalyzed by ruthenium(II) complexes of spirobifluorene diphosphine (SFDP) ligands, Adv. Synth. Catal. 2006, 348, 1271-1276.
9.Enantioselective Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids, Org. Lett. 2006, 8, 2567-2569.
10.Asymmetric Friedel-Crafts addition of indoles to N-sulfonyl aldimines: A simple approach to optically active 3-indolyl-methanamine derivatives, Org. Lett. 2006, 8, 1621-1624.
11.Enantioselective rhodium-catalyzed addition of arylboronic acids to aldehydes using chiral spiro monophosphite ligands, Org. Lett. 2006, 8, 1479-1481.
12.Highly enantioselective hydrovinylation of alpha-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters, J. Am. Chem. Soc. 2006, 128, 2780-2781
13.Asymmetric Friedel-crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes, J. Org. Chem. 2006, 71, 75-80.
14.Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols, Org. Lett. 2005, 7, 2333-2335.
15.Copper-catalyzed asymmetric ring opening of oxabicyclic alkenes with Grignard reagents, J. Org. Chem. 2005, 70, 3734-3736.
16.Ru(II)-SDP-complex-catalyzed asymmetric hydrogenation of ketones. Effect of the alkali metal cation in the reaction, J. Org. Chem. 2005, 70, 2967-2973.
17.Highly rigid diphosphane ligands with a large dihedral angle based on a chiral spirobifluorene backbone, Angew. Chem. Int. Ed. 2005, 44, 1118-1121.
18.Rhodium-catalyzed asymmetric Pauson-Khand reaction using monophosphoramidite ligand SIPHOS, Adv. Synth. Catal. 2005, 347, 759-762.
19.The application of SDP ligands for Pd-catalyzed allylic alkylation, Adv. Synth. Catal. 2004, 346, 625-632.
20.Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands, J. Org. Chem. 2004, 69, 4648-4655.
21.Highly efficient Suzuki cross-coupling catalyzed by palladium/ phosphine-imidazolium carbene system, Adv. Synth. Catal. 2004, 346, 595-598.
22.Synthesis and optical resolution of 9,9′-spirobifluorene-1,1′-diol, Org. Lett. 2004, 6, 2381-2383.
23.Synthesis of monodentate chiral spiro phosphonites and the electronic effect of ligand in asymmetric hydrogenation, J. Org. Chem. 2004, 69, 8157-8160.
24.Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using chiral spiro phosphoramidites as ligands, J. Org. Chem. 2003, 68, 1582-1584.
25.Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones, J. Am. Chem. Soc. 2003, 125, 4404-4405.
26.Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions, Chem. Commun. 2002, 480-481.
27. Monodentate chiral spiro phosphoramidites: Efficient ligands for rhodium-catalyzed enantioselective hydrogenation of enamides, Angew. Chem. Int. Ed. 2002, 41, 2348-2350.
